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Organic Synthesis: Strategy and Control A: Introduction: Selectivity 1. Planning Organic Syntheses: Tactics, Strategy, and Control 2. Chemoselectivity 3. Regioselectivity: Controlled Aldol Reactions 4. Stereoselectivity: Stereoselective Aldol Reactions 5. Alternative Strategies for Enone Synthesis 6. Choosing a Strategy : The Synthesis of cyclopentenones B: Making Carbon-Carbon Bonds. 7. The Ortho Strategy for Aromatic Compounds 8. ?-Complexes of Metals 9. Controlling the Michael Reaction 10. Specific Enol Equivalents 11. Extended Enolates 12. Allyl Anions 13. Homoenolates 14. Acyl Anion Equivalents C: Carbon-Carbon Double Bonds 15. Synthesis of Double Bonds of Defined Stereochemistry 16. Stereo-Controlled Vinyl Anion Equivalents 17. Electrophilic Attack on Alkenes 18. Vinyl Cations: Palladium-Catalysed C?C Coupling 19. Allyl Alcohols: Allyl Cation Equivalents (and More) D: Stereochemistry 20. Control of Stereochemistry ? Introduction 21 Controlling Relative Stereochemistry 22. Resolution 23. The Chiral Pool 24. Asymmetric Induction I: Reagent-Based Strategy 25. Asymmetric Induction II: Asymmetric Catalysis: Formation of C-O and C-N Bonds 26. Asymmetric Induction III: Asymmetric Catalysis: Formation of C-H and C-C Bonds 27. Asymmetric Induction IV: Substrate-Based Strategy 28. Kinetic Resolution 29. Enzymes: Biological Methods in Asymmetric Synthesis 30. New Chiral Centres from Old 31. Strategy of Asymmetric Synthesis E: Functional Group Strategy 32. Functionalisation of Pyridine 33. Oxidation of Aromatic Compounds, Enols and Enolates 34. Functionality and Pericyclic Reactions: Nitrogen Heterocycles by Cycloadditions and Sigmatropic Rearrangements 35. Synthesis and Chemistry of Azoles and other Heterocycles with Two or more Heteroatoms 36. Tandem Organic Reactions Appendix ? General References
Library of Congress Subject Headings for this publication:
Organic compounds -- Synthesis.
Stereochemistry.