Exposure to some volatile organic compounds (VOCs) can accelerate oxidation and hydrolysis in collection materials, evidenced by discoloration and other degradation. VOCs can come from external sources, such as outside (make-up) air, and internal sources, such as copying equipment and materials used in buildings, exhibit cases, frames or furniture, including paint, wood, plastics, or fabrics. Sometimes VOCs are emitted by collections themselves.
Wherever possible, exposure of collections to VOCs should be limited. Best practices dictate that only the most stable materials be used in proximity to collections. This means limiting VOCs known to damage collections to the levels listed below:
Table 1: Maximum Permitted Air Pollution after Filtration (in parts per billion)1
Sulfur dioxide |
Nitrogen dioxide |
Ozone |
Formaldehyde |
Acetic acid |
|---|---|---|---|---|
1.0 ppb |
2.6 ppb |
4.0 ppb |
4.0 ppb |
4.0 ppb |
Table 2: Unstable Housing, Case, and Construction Materials2
Acidic materials |
Volatile acids |
Oils |
Formaldehydes |
Other |
|---|---|---|---|---|
Acid-curing silicones, sealants, and adhesives Materials containing asbestos, sulfur or lead |
Vinyls, including, but not limited to, unstable chlorine-containing polymers (e.g. polyvinyl chloride (PVC), vinylidene chloride) Polyurethane-based products, including, but not limited to, paints, varnishes, and foams Pressure-sensitive adhesives that release VOCs Materials containing cellulose nitrate (e.g. lacquers and adhesives) Fabrics and films containing cellulose acetate |
Oil-based paints or varnishes Modified alkyd paints |
Any material that emits formaldehyde (urea, phenol, resorcinol, formaldehyde), including, but not limited to, plywood, particle board, hardboard, and plastic laminates |
silk wood |
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1 Values from NARA 1571, Archival Storage Standards, February 15, 2002. http://www.archives.gov/foia/directives/nara1571.pdf, [PDF 94.6 K / 16 p.] accessed 1/30/09. For a helpful summary of prohibited materials, good practice for collections environments at every scale, and environmental storage standards, see this document from the National Archives and Records Administration.
2Content from von Endt, D., Erhardt, W.D., and Hopwood, W.R. 1995. Evaluating Materials Used for Constructing Storage Cases. In: Storage of Natural History Collections: A Preventive Conservation Approach, editors, C.L. Rose, C.A. Hawks, and H.H. Genoways, 269-282. Pittsburgh, PA: Society for the Preservation of Natural History Collections.
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